Criteria and Air-Toxic Emissions from In-Use Automobiles in the National Low-Emission Vehicle Program

Abstract

The U.S. Environmental Protection Agency (EPA) implemented a program to identify tailpipe emissions of criteria and air-toxic contaminants from in-use, light-duty low-emission vehicles (LEVs). EPA recruited 25 LEVs in 2002 and measured emissions on a chassis dynamometer using the cold-start urban dynamometer driving schedule of the Federal Test Procedure. The emissions measured included regulated pollutants, particulate matter, speciated hydrocarbon compounds, and carbonyl compounds. The results provided a comparison of emissions from real-world LEVs with emission standards for criteria and air-toxic compounds. Emission measurements indicated that a portion of the in-use fleet tested exceeded standards for the criteria gases. Real-time regulated and speciated hydrocarbon measurements demonstrated that the majority of emissions occurred during the initial phases of the cold-start portion of the urban dynamometer driving schedule. Overall, the study provided updated emission factor data for real-world, in-use operation of LEVs for improved emissions modeling and mobile source inventory development.     

Importance of Moisture on Stomatal Behavior Of Plants Subjected to Ozone

The stomatal resistance, measured with a ventilated diffusion porometer at various times before, during, and after exposure to 20–25 pphm ozone, was followed in water-stressed or well-watered beans, beans exposed at either low (37%) or high (73%) atmospheric humidity, and two tobacco cultivars exposed at the same two humidities. The two tobacco cultivars that were compared were the 0₃-susceptible Bel W-3 and the 0₃-resistant Consolidated L. The stomata of the water-stressed but unwilted bean plants closed quickly from a resistance of 2.9 ± 0.3 sec/cm to 8.4 ± 1.0 sec/cm when exposed to O₃ whereas those in the unstressed plants closed slowly from a resistance of 2.5 ± 0.6 sec/cm to 5.2 ± 0.8 sec/cm after exposure to O3 for 10 min. Exposure to 0₃ for 30 min in the moist atmosphere caused no change in stomatal resistance of the bean plants whereas in the dry atmosphere the stomata closed from a resistance of 3.7 ± 0.4 sec/cm to 6.7 ± 0.6 sec/cm, but opened again when ozonation was terminated. With tobacco exposed to O₃ in a dry atmosphere the stomata of the 0₃-resistant cultivar closed more rapidly than the 0₃-susceptible variety, whereas in a moist atmosphere the stomata of both cultivars closed slowly and equally during the 60 min of ozonation.     

Effects of past and present livestock grazing on herpetofauna in a landscape‐scale experiment

Livestock grazing is the most widespread land use on Earth and can have negative effects on biodiversity. Yet, many of the mechanisms by which grazing leads to changes in biodiversity remain unresolved. One reason is that conventional grazing studies often target broad treatments rather than specific parameters of grazing (e.g., intensity, duration, and frequency) or fail to account for historical grazing effects. We conducted a landscape‐scale replicated grazing experiment (15,000 km², 97 sites) to examine the impact of past grazing management and current grazing regimes (intensity, duration, and frequency) on a community of ground‐dwelling herpetofauna (39 species). We analyzed community variables (species richness and composition) for all species and built multiseason patch‐occupancy models to predict local colonization and extinction for the 7 most abundant species. Past grazing practices did not influence community richness but did affect community composition and patch colonization and extinction for 4 of 7 species. Present grazing parameters did not influence community richness or composition, but 6 of the 7 target species were affected by at least one grazing parameter. Grazing frequency had the most consistent influence, positively affecting 3 of 7 species (increased colonization or decreased extinction). Past grazing practice affected community composition and population dynamics in some species in different ways, which suggests that conservation planners should examine the different grazing histories of an area. Species responded differently to specific current grazing practices; thus, incentive programs that apply a diversity of approaches rather than focusing on a change such as reduced grazing intensity should be considered. Based on our findings, we suggest that determining fine‐scale grazing attributes is essential for advancing grazing as a conservation strategy.     

A summary of environmental legislation targeting disposable diapers and review of related literature

In recent years state and local governments, as well as private citizens, have become very concerned about the mounting solid waste disposal problem facing our nation. Special concern has been expressed over the presence of disposable diapers in the solid waste stream. Responding to the concerns, legislators in at least 25 states proposed actions regarding disposable diapers between 1990 and 1992. Several factors contributed to the number of legislative proposals regarding disposable diapers over the past few years. First was the public's and legislators' misconception about the contribution of disposable diapers to the solid waste stream. Second was an erroneous assumption held by the public and some legislators that biodegradation readily occurs in landfills. Third was the desire to increase demand for agricultural products by requiring the use of degradable products. These contributing factors and other issues surrounding the proposal and passage of environmental legislation pertaining to disposable diapers are presented in this paper and the relevant literature is summarized. To provide the necessary context, the paper contains a review of the literature concerning disposable diapers, their composition and usage; and their environmental impact and fate and a comparison of their performance and cost to those of cloth diapers.     

Ecological effects of density-independent mortality: application to cooling-water withdrawals.

A wide variety of environmental stresses can cause density-independent mortality in species populations. One example is cooling-water withdrawals, which kill or injure many aquatic organisms near power plants and other industrial facilities. In the United States alone, hundreds of facilities withdraw trillions of gallons from inland and coastal waters every year to cool turbines and other manufacturing equipment. A number of detailed, site-specific studies of the effects of such cooling-water withdrawals have been conducted over the last 30 years, but only a few generalizations have been proposed in the peer-reviewed literature. In this paper we use a series of basic theoretical models to investigate the potential effects of density-independent mortality on species populations and ecosystems, with particular focus on the effects of cooling-water withdrawals on fish populations, fisheries, and aquatic communities. Among other results, we show that the effects of cooling-water withdrawals on a species will depend on the magnitude of other co-occurring stressors, environmental variability, the nature of the management regime in the associated fisheries, and the position of the species in the food web. The general models in this paper can provide a starting point for further empirical case studies and some preliminary conceptual guidance for decision makers who must choose between alternative policy options for controlling cooling-water withdrawals.     

Tracer studies to characterize the effects of roadside noise barriers on near-road pollutant dispersion under varying atmospheric stability conditions

A roadway toxics dispersion study was conducted at the Idaho National Laboratory (INL) to document the effects on concentrations of roadway emissions behind a roadside sound barrier in various conditions of atmospheric stability. The homogeneous fetch of the INL, controlled emission source, lack of other manmade or natural flow obstructions, and absence of vehicle-generated turbulence reduced the ambiguities in interpretation of the data. Roadway emissions were simulated by the release of an atmospheric tracer (SF₆) from two 54 m long line sources, one for an experiment with a 90 m long noise barrier and one for a control experiment without a barrier. Simultaneous near-surface tracer concentration measurements were made with bag samplers on identical sampling grids downwind from the line sources. An array of six 3-d sonic anemometers was employed to measure the barrier-induced turbulence. Key findings of the study are: (1) the areal extent of higher concentrations and the absolute magnitudes of the concentrations both increased as atmospheric stability increased; (2) a concentration deficit developed in the wake zone of the barrier with respect to concentrations at the same relative locations on the control experiment at all atmospheric stabilities; (3) lateral dispersion was significantly greater on the barrier grid than the non-barrier grid; and (4) the barrier tended to trap high concentrations near the “roadway” (i.e. upwind of the barrier) in low wind speed conditions, especially in stable conditions.     

Evaluation of the best compromise between the urban air quality monitoring resolution by diffusive sampling and resource requirements

The need to collect data representative of overall urban pollution is all-important in order to monitor the population exposure. High spatial resolution monitoring using diffusive samplers allows studying of the urban pollutant distribution, thus enabling deeper investigation of their generation and diffusion mechanisms. Nevertheless, such a monitoring campaign has a certain cost. In this study we point out how to find the best compromise between the number of necessary measurements and the affordable costs for monitoring campaigns. We also describe an innovative method for the proper design of a fixed urban monitoring network by means of preliminary high spatial resolution campaigns using diffusive samplers. Four European capital cities (Dublin, Madrid, Paris and Rome) were monitored six times, each time for seven days. Benzene, toluene, ethylbenzene, xylenes (BTEX) and NO(2) concentrations were measured at 146 sites in Dublin, 293 in Madrid, 339 in Paris and 290 in Rome. Multiscale grids have been drawn which ranged in mesh size from 500 m to 2 km. The statistical processing of data produced a twofold result: the creation of isoconcentration maps with geostatistical procedures, and an algorithm aimed at locating the minimum number of sampling sites where the fixed monitoring stations should be placed. Average urban levels estimated on the basis of these selected sites differ by less than 8% from those calculated on the whole populations of the sampled points. The aim of this work is to investigate how far the resolution of a monitoring campaign of urban pollution by diffusive sampling can be reduced, thus making the monitoring less expensive in terms of human and financial resources, while preserving the same quality of the results that could be achieved with a higher resolution. We found that there is no significant loss of information when the resolution of the monitoring grid for BTEX is lowered to a mesh size of 1.85 km, that is a sampling site each 3.4 km(2), and that the minimum number of sampling sites to be used is N = 0.29 A, where A is the urban surface to be monitored (in km(2)). As the spatial distribution of NO(2) is less sensitive to the distance from the emission source than that of BTEX, this relationship could be retained as a valid lower limit for the mesh grid size also for NO(2) monitoring.